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Physical Chemistry of Solutions

General data

Course ID: 1600-DLER6PCS
Erasmus code / ISCED: (unknown) / (0531) Chemistry The ISCED (International Standard Classification of Education) code has been designed by UNESCO.
Course title: Physical Chemistry of Solutions
Name in Polish: Physical Chemistry of Solutions
Organizational unit: Faculty of Chemistry
Course groups:
ECTS credit allocation (and other scores): 0 OR 4.00 (depends on study program) Basic information on ECTS credits allocation principles:
  • the annual hourly workload of the student’s work required to achieve the expected learning outcomes for a given stage is 1500-1800h, corresponding to 60 ECTS;
  • the student’s weekly hourly workload is 45 h;
  • 1 ECTS point corresponds to 25-30 hours of student work needed to achieve the assumed learning outcomes;
  • weekly student workload necessary to achieve the assumed learning outcomes allows to obtain 1.5 ECTS;
  • work required to pass the course, which has been assigned 3 ECTS, constitutes 10% of the semester student load.
view allocation of credits
Language: Polish
Prerequisits:

Student

knows:

basic terms and laws of general and physical chemistry

basics of higher mathematics

basic law of physics

can:

calculate derivatives and integrals
Short description:

The aim of the course is extension of the knowledge concerning solution thermodynamics, acquisition of information about colloidal systems their properties role in our world.
Learning outcomes:

Student:

E1. Defines partial molar and excess thermodynamic functions, chemical potentials and thermodynamic functions of mixing.

16C-1A_W05, 16C-1A_W09, 16C-1A_W11

E2. Calculates values of thermodynamic functions which characterize state of solutions components and relations between them on the basis of the experimental data. Interpret obtained results.

16C-1A_U08, 16C-1A_K03

E3. Defines ideal solutions and adduces laws that describe behaviour of such a solutions, distinguishes ideal and real solutions. Itemize types of deviations from ideality and explain their origin.

16C-1A_W09, 16C-1A_W05, 16C-1A_W11

E4. Explains activity and activity coefficients terms.

16C-1A_U01

E5. Determines experimentally values of thermodynamics functions characterizing system.

16C-1A_U01

E6. Calculate values of activity coefficients on the basis of experimental data.

16C-1A_U08, 16C-1A_K03, 16C-1A_W11

E7. Defines colloidal systems. Identifies colloidal systems in his ambient. Perceives and describes phenomena typical for colloidal systems

16C-1A_W05, 16C-1A_W09, 16C-1A_W11,16C-1A_U01

E8. Determine parameter of micellization using different experimental methods.

16C-1A_U01

E9. Uses specialist literature and evaluate critically knowledge obtained from different sources, browses necessary information in the specialist literature also in foreign languages

16C-1A_U09, 16C-1A_K06, 16C-1A_K05

Classes in period "Summer Semester 2024/2025" (future)

Time span: 2025-02-17 - 2025-09-30
Selected timetable range:
Navigate to timetable
Type of class:
Discussion class, 14 hours more information
Laboratory, 20 hours more information
Lecture, 20 hours more information
Coordinators: Michał Wasiak
Group instructors: (unknown)
Students list: (inaccessible to you)
Examination: (in Polish) Ocena zgodna z regulaminem studiów
(in Polish) Czy IRK BWZ?:

(in Polish) T
Teaching Method:

Lecture – verbal methods adducing and hint methods, showing methods: traditional lecture and seminar lecture with multimedia presentation

Seminar - verbal hint methods, problem-solving, practical methods, activating methods

Laboratory - practical methods, activating methods
Method and Criteria of Assessment:

The grade of seminar consists of: grades from one written mid-term test evaluating the effects of training in the knowledge and skills: (E1-E6,E9).

Assessment of laboratory consist of performance of 4 exercises, elaboration of the results in the form of a written report and a grade from a test valuating the effects of training in the knowledge and skills: (E1-E8).

The grade of the lecture consists of grade written test evaluating the effects of training (E1,E3 - E5,E7 - E8) (50%).

The final grade is mean value of grade from lecture(20%) and from seminar (40%) and laboratory (40%).
Course Content:

Thermodynamic of solutions. Partial molar quantities. Gibbs-Duhem, Duhem-Margules relations. Methods of determination of partial molar quantities on the basis of experimental data and the relations between them. Chemical potentials. Temperature and pressure dependence of chemical potentials in case of gases and condensed phases. Mixing functions of ideal solutions gaseous and liquid. Ideal solutions - Raoults law, and ideal-dilute solutions - Henry's law. Colligative properties. Real solutions - deviations from ideality. Excess functions. Activities and activity coefficients. Determination of activity coefficients on the basis of vapour pressure measurements. Activity scales. Reference states and standard states. Temperature and pressure dependence of activity coefficients. Osmotic coefficient.

Colloidal systems. Classification of colloid systems. Properties of colloid solutions.
Bibliography:

1. H. Buchowski, W. Ufnalski, Roztwory, Wydawnictwa Naukowo-Techniczne, Warszawa 1995

2. P.W. Atkins, Chemia Fizyczna, Wydawnictwo Naukowe PWN, Warszawa 2001

3. P.W. Atkins, C.A. Trapp, M.P. Cady, C. Glunta, Chemia fizyczna, Zbiór zadań z rozwiązaniami, Wydawnictwo Naukowe PWN, Warszawa 2001

4. J. Szarawara, Termodynamika chemiczna stosowana, Wydawnictwa Naukowo-Techniczne, Warszawa 1997

5. W.T. Dutkiewicz, Fizykochemia Powierzchni, Wydawnictwa Naukowo-Techniczne, Warszawa 1998

Classes in period "Summer Semester 2023/2024" (in progress)

Time span: 2024-02-26 - 2024-09-30
Selected timetable range:
Navigate to timetable
Type of class:
Discussion class, 14 hours more information
Laboratory, 20 hours more information
Lecture, 20 hours more information
Coordinators: Michał Wasiak
Group instructors: (unknown)
Students list: (inaccessible to you)
Examination: (in Polish) Ocena zgodna z regulaminem studiów
(in Polish) Czy IRK BWZ?:

(in Polish) T
Teaching Method:

Lecture – verbal methods adducing and hint methods, showing methods: traditional lecture and seminar lecture with multimedia presentation

Seminar - verbal hint methods, problem-solving, practical methods, activating methods

Laboratory - practical methods, activating methods
Method and Criteria of Assessment:

The grade of seminar consists of: grades from one written mid-term test evaluating the effects of training in the knowledge and skills: (E1-E6,E9).

Assessment of laboratory consist of performance of 4 exercises, elaboration of the results in the form of a written report and a grade from a test valuating the effects of training in the knowledge and skills: (E1-E8).

The grade of the lecture consists of grade written test evaluating the effects of training (E1,E3 - E5,E7 - E8) (50%).

The final grade is mean value of grade from lecture(20%) and from seminar (40%) and laboratory (40%).
Course Content:

Thermodynamic of solutions. Partial molar quantities. Gibbs-Duhem, Duhem-Margules relations. Methods of determination of partial molar quantities on the basis of experimental data and the relations between them. Chemical potentials. Temperature and pressure dependence of chemical potentials in case of gases and condensed phases. Mixing functions of ideal solutions gaseous and liquid. Ideal solutions - Raoults law, and ideal-dilute solutions - Henry's law. Colligative properties. Real solutions - deviations from ideality. Excess functions. Activities and activity coefficients. Determination of activity coefficients on the basis of vapour pressure measurements. Activity scales. Reference states and standard states. Temperature and pressure dependence of activity coefficients. Osmotic coefficient.

Colloidal systems. Classification of colloid systems. Properties of colloid solutions.
Bibliography:

1. H. Buchowski, W. Ufnalski, Roztwory, Wydawnictwa Naukowo-Techniczne, Warszawa 1995

2. P.W. Atkins, Chemia Fizyczna, Wydawnictwo Naukowe PWN, Warszawa 2001

3. P.W. Atkins, C.A. Trapp, M.P. Cady, C. Glunta, Chemia fizyczna, Zbiór zadań z rozwiązaniami, Wydawnictwo Naukowe PWN, Warszawa 2001

4. J. Szarawara, Termodynamika chemiczna stosowana, Wydawnictwa Naukowo-Techniczne, Warszawa 1997

5. W.T. Dutkiewicz, Fizykochemia Powierzchni, Wydawnictwa Naukowo-Techniczne, Warszawa 1998

Classes in period "Summer Semester 2022/2023" (past)

Time span: 2023-02-20 - 2023-09-30
Selected timetable range:
Navigate to timetable
Type of class:
Discussion class, 14 hours more information
Laboratory, 20 hours more information
Lecture, 20 hours more information
Coordinators: Michał Wasiak
Group instructors: (unknown)
Students list: (inaccessible to you)
Examination: (in Polish) Ocena zgodna z regulaminem studiów
(in Polish) Czy IRK BWZ?:

(in Polish) T
Teaching Method:

Lecture – verbal methods adducing and hint methods, showing methods: traditional lecture and seminar lecture with multimedia presentation

Seminar - verbal hint methods, problem-solving, practical methods, activating methods

Laboratory - practical methods, activating methods
Method and Criteria of Assessment:

The grade of seminar consists of: grades from one written mid-term test evaluating the effects of training in the knowledge and skills: (E1-E6,E9).

Assessment of laboratory consist of performance of 4 exercises, elaboration of the results in the form of a written report and a grade from a test valuating the effects of training in the knowledge and skills: (E1-E8).

The grade of the lecture consists of grade written test evaluating the effects of training (E1,E3 - E5,E7 - E8) (50%).

The final grade is mean value of grade from lecture(20%) and from seminar (40%) and laboratory (40%).
Course Content:

Thermodynamic of solutions. Partial molar quantities. Gibbs-Duhem, Duhem-Margules relations. Methods of determination of partial molar quantities on the basis of experimental data and the relations between them. Chemical potentials. Temperature and pressure dependence of chemical potentials in case of gases and condensed phases. Mixing functions of ideal solutions gaseous and liquid. Ideal solutions - Raoults law, and ideal-dilute solutions - Henry's law. Colligative properties. Real solutions - deviations from ideality. Excess functions. Activities and activity coefficients. Determination of activity coefficients on the basis of vapour pressure measurements. Activity scales. Reference states and standard states. Temperature and pressure dependence of activity coefficients. Osmotic coefficient.

Colloidal systems. Classification of colloid systems. Properties of colloid solutions.
Bibliography:

1. H. Buchowski, W. Ufnalski, Roztwory, Wydawnictwa Naukowo-Techniczne, Warszawa 1995

2. P.W. Atkins, Chemia Fizyczna, Wydawnictwo Naukowe PWN, Warszawa 2001

3. P.W. Atkins, C.A. Trapp, M.P. Cady, C. Glunta, Chemia fizyczna, Zbiór zadań z rozwiązaniami, Wydawnictwo Naukowe PWN, Warszawa 2001

4. J. Szarawara, Termodynamika chemiczna stosowana, Wydawnictwa Naukowo-Techniczne, Warszawa 1997

5. W.T. Dutkiewicz, Fizykochemia Powierzchni, Wydawnictwa Naukowo-Techniczne, Warszawa 1998

Classes in period "Summer Semester 2021/2022" (past)

Time span: 2022-02-21 - 2022-09-30
Selected timetable range:
Navigate to timetable
Type of class:
Discussion class, 14 hours more information
Laboratory, 20 hours more information
Lecture, 20 hours more information
Coordinators: Michał Wasiak
Group instructors: Magdalena Tyczyńska, Michał Wasiak
Students list: (inaccessible to you)
Examination: (in Polish) Ocena zgodna z regulaminem studiów
(in Polish) Czy IRK BWZ?:

(in Polish) T
Teaching Method:

Lecture – verbal methods adducing and hint methods, showing methods: traditional lecture and seminar lecture with multimedia presentation

Seminar - verbal hint methods, problem-solving, practical methods, activating methods

Laboratory - practical methods, activating methods
Method and Criteria of Assessment:

The grade of seminar consists of: grades from one written mid-term test evaluating the effects of training in the knowledge and skills: (E1-E6,E9).

Assessment of laboratory consist of performance of 4 exercises, elaboration of the results in the form of a written report and a grade from a test valuating the effects of training in the knowledge and skills: (E1-E8).

The grade of the lecture consists of grade written test evaluating the effects of training (E1,E3 - E5,E7 - E8) (50%).

The final grade is mean value of grade from lecture(20%) and from seminar (40%) and laboratory (40%).
Course Content:

Thermodynamic of solutions. Partial molar quantities. Gibbs-Duhem, Duhem-Margules relations. Methods of determination of partial molar quantities on the basis of experimental data and the relations between them. Chemical potentials. Temperature and pressure dependence of chemical potentials in case of gases and condensed phases. Mixing functions of ideal solutions gaseous and liquid. Ideal solutions - Raoults law, and ideal-dilute solutions - Henry's law. Colligative properties. Real solutions - deviations from ideality. Excess functions. Activities and activity coefficients. Determination of activity coefficients on the basis of vapour pressure measurements. Activity scales. Reference states and standard states. Temperature and pressure dependence of activity coefficients. Osmotic coefficient.

Colloidal systems. Classification of colloid systems. Properties of colloid solutions.
Bibliography:

1. H. Buchowski, W. Ufnalski, Roztwory, Wydawnictwa Naukowo-Techniczne, Warszawa 1995

2. P.W. Atkins, Chemia Fizyczna, Wydawnictwo Naukowe PWN, Warszawa 2001

3. P.W. Atkins, C.A. Trapp, M.P. Cady, C. Glunta, Chemia fizyczna, Zbiór zadań z rozwiązaniami, Wydawnictwo Naukowe PWN, Warszawa 2001

4. J. Szarawara, Termodynamika chemiczna stosowana, Wydawnictwa Naukowo-Techniczne, Warszawa 1997

5. W.T. Dutkiewicz, Fizykochemia Powierzchni, Wydawnictwa Naukowo-Techniczne, Warszawa 1998

Classes in period "Summer Semester 2020/2021" (past)

Time span: 2021-03-08 - 2021-09-30
Selected timetable range:
Navigate to timetable
Type of class:
Discussion class, 14 hours more information
Laboratory, 20 hours more information
Lecture, 20 hours more information
Coordinators: Michał Wasiak
Group instructors: Magdalena Tyczyńska, Michał Wasiak
Students list: (inaccessible to you)
Examination: Course - (in Polish) Ocena zgodna z regulaminem studiów
Discussion class - (in Polish) Ocena zgodna z regulaminem studiów
Laboratory - (in Polish) Ocena zgodna z regulaminem studiów
Lecture - (in Polish) Zaliczenie lub ocena
(in Polish) Czy IRK BWZ?:

(in Polish) T
Teaching Method:

Lecture – verbal methods adducing and hint methods, showing methods: traditional lecture and seminar lecture with multimedia presentation

Seminar - verbal hint methods, problem-solving, practical methods, activating methods

Laboratory - practical methods, activating methods
Method and Criteria of Assessment:

The grade of seminar consists of: grades from one written mid-term test evaluating the effects of training in the knowledge and skills: (E1-E6,E9).

Assessment of laboratory consist of performance of 4 exercises, elaboration of the results in the form of a written report and a grade from a test valuating the effects of training in the knowledge and skills: (E1-E8).

The grade of the lecture consists of grade written test evaluating the effects of training (E1,E3 - E5,E7 - E8) (50%).

The final grade is mean value of grade from lecture(20%) and from seminar (40%) and laboratory (40%).
Course Content:

Thermodynamic of solutions. Partial molar quantities. Gibbs-Duhem, Duhem-Margules relations. Methods of determination of partial molar quantities on the basis of experimental data and the relations between them. Chemical potentials. Temperature and pressure dependence of chemical potentials in case of gases and condensed phases. Mixing functions of ideal solutions gaseous and liquid. Ideal solutions - Raoults law, and ideal-dilute solutions - Henry's law. Colligative properties. Real solutions - deviations from ideality. Excess functions. Activities and activity coefficients. Determination of activity coefficients on the basis of vapour pressure measurements. Activity scales. Reference states and standard states. Temperature and pressure dependence of activity coefficients. Osmotic coefficient.

Colloidal systems. Classification of colloid systems. Properties of colloid solutions.
Bibliography:

1. H. Buchowski, W. Ufnalski, Roztwory, Wydawnictwa Naukowo-Techniczne, Warszawa 1995

2. P.W. Atkins, Chemia Fizyczna, Wydawnictwo Naukowe PWN, Warszawa 2001

3. P.W. Atkins, C.A. Trapp, M.P. Cady, C. Glunta, Chemia fizyczna, Zbiór zadań z rozwiązaniami, Wydawnictwo Naukowe PWN, Warszawa 2001

4. J. Szarawara, Termodynamika chemiczna stosowana, Wydawnictwa Naukowo-Techniczne, Warszawa 1997

5. W.T. Dutkiewicz, Fizykochemia Powierzchni, Wydawnictwa Naukowo-Techniczne, Warszawa 1998

Classes in period "Summer Semester 2019/2020" (past)

Time span: 2020-02-24 - 2020-09-30
Selected timetable range:
Navigate to timetable
Type of class:
Discussion class, 14 hours more information
Laboratory, 20 hours more information
Lecture, 20 hours more information
Coordinators: Michał Wasiak
Group instructors: (unknown)
Students list: (inaccessible to you)
Examination: Course - (in Polish) Ocena zgodna z regulaminem studiów
Discussion class - (in Polish) Ocena zgodna z regulaminem studiów
Laboratory - (in Polish) Ocena zgodna z regulaminem studiów
Lecture - (in Polish) Zaliczenie lub ocena
(in Polish) Czy IRK BWZ?:

(in Polish) T
Teaching Method:

Lecture – verbal methods adducing and hint methods, showing methods: traditional lecture and seminar lecture with multimedia presentation

Seminar - verbal hint methods, problem-solving, practical methods, activating methods

Laboratory - practical methods, activating methods
Method and Criteria of Assessment:

The grade of seminar consists of: grades from one written mid-term test evaluating the effects of training in the knowledge and skills: (E1-E6,E9).

Assessment of laboratory consist of performance of 4 exercises, elaboration of the results in the form of a written report and a grade from a test valuating the effects of training in the knowledge and skills: (E1-E8).

The grade of the lecture consists of grade written test evaluating the effects of training (E1,E3 - E5,E7 - E8) (50%).

The final grade is mean value of grade from lecture(20%) and from seminar (40%) and laboratory (40%).
Course Content:

Thermodynamic of solutions. Partial molar quantities. Gibbs-Duhem, Duhem-Margules relations. Methods of determination of partial molar quantities on the basis of experimental data and the relations between them. Chemical potentials. Temperature and pressure dependence of chemical potentials in case of gases and condensed phases. Mixing functions of ideal solutions gaseous and liquid. Ideal solutions - Raoults law, and ideal-dilute solutions - Henry's law. Colligative properties. Real solutions - deviations from ideality. Excess functions. Activities and activity coefficients. Determination of activity coefficients on the basis of vapour pressure measurements. Activity scales. Reference states and standard states. Temperature and pressure dependence of activity coefficients. Osmotic coefficient.

Colloidal systems. Classification of colloid systems. Properties of colloid solutions.
Bibliography:

1. H. Buchowski, W. Ufnalski, Roztwory, Wydawnictwa Naukowo-Techniczne, Warszawa 1995

2. P.W. Atkins, Chemia Fizyczna, Wydawnictwo Naukowe PWN, Warszawa 2001

3. P.W. Atkins, C.A. Trapp, M.P. Cady, C. Glunta, Chemia fizyczna, Zbiór zadań z rozwiązaniami, Wydawnictwo Naukowe PWN, Warszawa 2001

4. J. Szarawara, Termodynamika chemiczna stosowana, Wydawnictwa Naukowo-Techniczne, Warszawa 1997

5. W.T. Dutkiewicz, Fizykochemia Powierzchni, Wydawnictwa Naukowo-Techniczne, Warszawa 1998

Classes in period "Summer Semester 2018/2019" (past)

Time span: 2019-02-18 - 2019-09-30
Selected timetable range:
Navigate to timetable
Type of class:
Discussion class, 14 hours more information
Laboratory, 20 hours more information
Lecture, 20 hours more information
Coordinators: Michał Wasiak
Group instructors: (unknown)
Students list: (inaccessible to you)
Examination: Course - (in Polish) Ocena zgodna z regulaminem studiów
Discussion class - (in Polish) Ocena zgodna z regulaminem studiów
Laboratory - (in Polish) Ocena zgodna z regulaminem studiów
Lecture - (in Polish) Zaliczenie lub ocena
(in Polish) Czy IRK BWZ?:

(in Polish) T
Teaching Method:

Lecture – verbal methods adducing and hint methods, showing methods: traditional lecture and seminar lecture with multimedia presentation

Seminar - verbal hint methods, problem-solving, practical methods, activating methods

Laboratory - practical methods, activating methods
Method and Criteria of Assessment:

The grade of seminar consists of: grades from one written mid-term test evaluating the effects of training in the knowledge and skills: (E1-E6,E9).

Assessment of laboratory consist of performance of 4 exercises, elaboration of the results in the form of a written report and a grade from a test valuating the effects of training in the knowledge and skills: (E1-E8).

The grade of the lecture consists of grade written test evaluating the effects of training (E1,E3 - E5,E7 - E8) (50%).

The final grade is mean value of grade from lecture(20%) and from seminar (40%) and laboratory (40%).
Course Content:

Thermodynamic of solutions. Partial molar quantities. Gibbs-Duhem, Duhem-Margules relations. Methods of determination of partial molar quantities on the basis of experimental data and the relations between them. Chemical potentials. Temperature and pressure dependence of chemical potentials in case of gases and condensed phases. Mixing functions of ideal solutions gaseous and liquid. Ideal solutions - Raoults law, and ideal-dilute solutions - Henry's law. Colligative properties. Real solutions - deviations from ideality. Excess functions. Activities and activity coefficients. Determination of activity coefficients on the basis of vapour pressure measurements. Activity scales. Reference states and standard states. Temperature and pressure dependence of activity coefficients. Osmotic coefficient.

Colloidal systems. Classification of colloid systems. Properties of colloid solutions.
Bibliography:

1. H. Buchowski, W. Ufnalski, Roztwory, Wydawnictwa Naukowo-Techniczne, Warszawa 1995

2. P.W. Atkins, Chemia Fizyczna, Wydawnictwo Naukowe PWN, Warszawa 2001

3. P.W. Atkins, C.A. Trapp, M.P. Cady, C. Glunta, Chemia fizyczna, Zbiór zadań z rozwiązaniami, Wydawnictwo Naukowe PWN, Warszawa 2001

4. J. Szarawara, Termodynamika chemiczna stosowana, Wydawnictwa Naukowo-Techniczne, Warszawa 1997

5. W.T. Dutkiewicz, Fizykochemia Powierzchni, Wydawnictwa Naukowo-Techniczne, Warszawa 1998
Course descriptions are protected by copyright.
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