Organic Chemistry B1A

(in Polish) T

(in Polish) Feeding methods

 informative lecture

 explanation or clarification.

Seeking methods:

 laboratory exercises, experimets

observation and measurement

Exposing methods: demonstration

(in Polish) The grade of the lecture consist of evaluation of written examination (50%) evaluating the effects of training in the knowledge and the laboratory exercises with written reports, (25%), classes (problem solving exercises) (25%).

A prerequisite for the exam aproach is to obtain credit from the laboratory and classes.

Effects of training in the collaborative work will be evaluated during laboratory exercises.

(in Polish) Written exam.

Written exerice reports

(in Polish) Lecture:

1) Alkanes and cycloalkanes. Cracking processes. Radical substitution reactions, halogenation of C (sp3)-H.

2) Halogen derivatives of alkanes, the polarization of the CX bond. Grignard reagents, nucleophilic substitution, nucleophilic reagents and their reactivity. Basicity and nucleophilicity. Mechanisms of nucleofilic substitution SN1, SN2 and elimination reactions E1 and E2. Zaitsev rule.

3) Alkenes and cycloalkenes. Geometric isomerism. Halogenation - electrophilic addition reactions, addition of HX reagents, reactions with oxidizing agents, free-radical polymerization, catalytic hydrogenation of alkenes. The stereochemistry of electrophilic addition reaction. The regiochemistry of HX addition to unsymmetrically substituted alkenes.

4) Alkynes. Reactions with HX reagents; catalyzed addition of water. Acidity of terminal alkynes; reactions with Grignard reagents

5) Dienes - structure, types. Conjugated dienes - isomerism s-cis and s-trans. Mesomerism. Electrophilic reagent addition reactions to conjugated dienes. Diels-Alder reaction.

6) Aromatic compounds, the concept of aromaticity, Hückel rule, resonance energy. reactivity of aromatic compounds. Electrophilic substitution: halogenation, nitration, sulfonation, alkylation, arylation. The role of the Lewis acid in electrophilic substitution. Electrophilic substitution mechanism. Isomerism of disubstituted benzene derivatives.

7) Alcohols and phenols. Effect of functional group-OH on the physico-chemical properties of alcohols, hydrogen bonding. Elimination and substitution reactions in a series of alcohols. The reactivity of the-OH: acidity, esterification, oxidation of alcohols. Polyhydroxy compounds. Acidity of phenols.

8)Ethers and epoxides. Thiols and sulfides. Synthesis, structure and reactivity.

9) Aliphatic and aromatic amines. Structure and bonding in amines. Basicity of amines - the impact of structure on the basicity of amines. Acylation of amines. Quaternary ammonium salts. The synthesis and reactions of arene diazonium salts. Azo dyes.

10) Aldehydes and ketones. The structure of the carbonyl group. Redox reactions. Nucleophilic addition of nucleophiles using nitrogen, oxygen, and carbon. The concept CH acidity, keto-enol tautomerism. Aldol-type condensations.

11) Aliphatic and aromatic carboxylic acids. The structure of a carboxyl group, a hydrogen bond in the carboxylic acids. Substituents effect on acidity, influence of inductive and mesomeric effect. The reactivity of the carboxyl group, esterification reaction, hydrolysis of esters.

12) Carboxylic acid derivatives and nucleophilic acyl substitution reactions. Chemistry of: acid halides, acid anhydrides, esters, amides, nitriles

Seminar / Class:

The aim of the seminar is to discuss the basic concepts presented during the lecture. Problem solving-classes teach how to apply the organic chemistry knowledge to solve the problems.

Laboratory:

1) Selection of a solvent for crystallization, crystallization of the substance, identification of substance using the melting point.

2) Distillation of the unknown substance and its identification using the boiling point and refractive index, separation of substances by the fractional distillation.

3) Separation of two substances by extraction.

4) The separation of the two substances by chromatography.

5) Synthesis of the three selected compounds

(in Polish) T

(in Polish) Feeding methods

 informative lecture

 explanation or clarification.

Seeking methods:

 laboratory exercises, experimets

observation and measurement

Exposing methods: demonstration

(in Polish) The grade of the lecture consist of evaluation of written examination (50%) evaluating the effects of training in the knowledge and the laboratory exercises with written reports, (25%), classes (problem solving exercises) (25%).

A prerequisite for the exam aproach is to obtain credit from the laboratory and classes.

Effects of training in the collaborative work will be evaluated during laboratory exercises.

(in Polish) Written exam.

Written exerice reports

(in Polish) Lecture:

1) Alkanes and cycloalkanes. Cracking processes. Radical substitution reactions, halogenation of C (sp3)-H.

2) Halogen derivatives of alkanes, the polarization of the CX bond. Grignard reagents, nucleophilic substitution, nucleophilic reagents and their reactivity. Basicity and nucleophilicity. Mechanisms of nucleofilic substitution SN1, SN2 and elimination reactions E1 and E2. Zaitsev rule.

3) Alkenes and cycloalkenes. Geometric isomerism. Halogenation - electrophilic addition reactions, addition of HX reagents, reactions with oxidizing agents, free-radical polymerization, catalytic hydrogenation of alkenes. The stereochemistry of electrophilic addition reaction. The regiochemistry of HX addition to unsymmetrically substituted alkenes.

4) Alkynes. Reactions with HX reagents; catalyzed addition of water. Acidity of terminal alkynes; reactions with Grignard reagents

5) Dienes - structure, types. Conjugated dienes - isomerism s-cis and s-trans. Mesomerism. Electrophilic reagent addition reactions to conjugated dienes. Diels-Alder reaction.

6) Aromatic compounds, the concept of aromaticity, Hückel rule, resonance energy. reactivity of aromatic compounds. Electrophilic substitution: halogenation, nitration, sulfonation, alkylation, arylation. The role of the Lewis acid in electrophilic substitution. Electrophilic substitution mechanism. Isomerism of disubstituted benzene derivatives.

7) Alcohols and phenols. Effect of functional group-OH on the physico-chemical properties of alcohols, hydrogen bonding. Elimination and substitution reactions in a series of alcohols. The reactivity of the-OH: acidity, esterification, oxidation of alcohols. Polyhydroxy compounds. Acidity of phenols.

8)Ethers and epoxides. Thiols and sulfides. Synthesis, structure and reactivity.

9) Aliphatic and aromatic amines. Structure and bonding in amines. Basicity of amines - the impact of structure on the basicity of amines. Acylation of amines. Quaternary ammonium salts. The synthesis and reactions of arene diazonium salts. Azo dyes.

10) Aldehydes and ketones. The structure of the carbonyl group. Redox reactions. Nucleophilic addition of nucleophiles using nitrogen, oxygen, and carbon. The concept CH acidity, keto-enol tautomerism. Aldol-type condensations.

11) Aliphatic and aromatic carboxylic acids. The structure of a carboxyl group, a hydrogen bond in the carboxylic acids. Substituents effect on acidity, influence of inductive and mesomeric effect. The reactivity of the carboxyl group, esterification reaction, hydrolysis of esters.

12) Carboxylic acid derivatives and nucleophilic acyl substitution reactions. Chemistry of: acid halides, acid anhydrides, esters, amides, nitriles

Seminar / Class:

The aim of the seminar is to discuss the basic concepts presented during the lecture. Problem solving-classes teach how to apply the organic chemistry knowledge to solve the problems.

Laboratory:

1) Selection of a solvent for crystallization, crystallization of the substance, identification of substance using the melting point.

2) Distillation of the unknown substance and its identification using the boiling point and refractive index, separation of substances by the fractional distillation.

3) Separation of two substances by extraction.

4) The separation of the two substances by chromatography.

5) Synthesis of the three selected compounds

(in Polish) T

(in Polish) Feeding methods

 informative lecture

 explanation or clarification.

Seeking methods:

 laboratory exercises, experimets

observation and measurement

Exposing methods: demonstration

(in Polish) The grade of the lecture consist of evaluation of written examination (50%) evaluating the effects of training in the knowledge and the laboratory exercises with written reports, (25%), classes (problem solving exercises) (25%).

A prerequisite for the exam aproach is to obtain credit from the laboratory and classes.

Effects of training in the collaborative work will be evaluated during laboratory exercises.

(in Polish) Written exam.

Written exerice reports

(in Polish) Lecture:

1) Alkanes and cycloalkanes. Cracking processes. Radical substitution reactions, halogenation of C (sp3)-H.

2) Halogen derivatives of alkanes, the polarization of the CX bond. Grignard reagents, nucleophilic substitution, nucleophilic reagents and their reactivity. Basicity and nucleophilicity. Mechanisms of nucleofilic substitution SN1, SN2 and elimination reactions E1 and E2. Zaitsev rule.

3) Alkenes and cycloalkenes. Geometric isomerism. Halogenation - electrophilic addition reactions, addition of HX reagents, reactions with oxidizing agents, free-radical polymerization, catalytic hydrogenation of alkenes. The stereochemistry of electrophilic addition reaction. The regiochemistry of HX addition to unsymmetrically substituted alkenes.

4) Alkynes. Reactions with HX reagents; catalyzed addition of water. Acidity of terminal alkynes; reactions with Grignard reagents

5) Dienes - structure, types. Conjugated dienes - isomerism s-cis and s-trans. Mesomerism. Electrophilic reagent addition reactions to conjugated dienes. Diels-Alder reaction.

6) Aromatic compounds, the concept of aromaticity, Hückel rule, resonance energy. reactivity of aromatic compounds. Electrophilic substitution: halogenation, nitration, sulfonation, alkylation, arylation. The role of the Lewis acid in electrophilic substitution. Electrophilic substitution mechanism. Isomerism of disubstituted benzene derivatives.

7) Alcohols and phenols. Effect of functional group-OH on the physico-chemical properties of alcohols, hydrogen bonding. Elimination and substitution reactions in a series of alcohols. The reactivity of the-OH: acidity, esterification, oxidation of alcohols. Polyhydroxy compounds. Acidity of phenols.

8)Ethers and epoxides. Thiols and sulfides. Synthesis, structure and reactivity.

9) Aliphatic and aromatic amines. Structure and bonding in amines. Basicity of amines - the impact of structure on the basicity of amines. Acylation of amines. Quaternary ammonium salts. The synthesis and reactions of arene diazonium salts. Azo dyes.

10) Aldehydes and ketones. The structure of the carbonyl group. Redox reactions. Nucleophilic addition of nucleophiles using nitrogen, oxygen, and carbon. The concept CH acidity, keto-enol tautomerism. Aldol-type condensations.

11) Aliphatic and aromatic carboxylic acids. The structure of a carboxyl group, a hydrogen bond in the carboxylic acids. Substituents effect on acidity, influence of inductive and mesomeric effect. The reactivity of the carboxyl group, esterification reaction, hydrolysis of esters.

12) Carboxylic acid derivatives and nucleophilic acyl substitution reactions. Chemistry of: acid halides, acid anhydrides, esters, amides, nitriles

Seminar / Class:

The aim of the seminar is to discuss the basic concepts presented during the lecture. Problem solving-classes teach how to apply the organic chemistry knowledge to solve the problems.

Laboratory:

1) Selection of a solvent for crystallization, crystallization of the substance, identification of substance using the melting point.

2) Distillation of the unknown substance and its identification using the boiling point and refractive index, separation of substances by the fractional distillation.

3) Separation of two substances by extraction.

4) The separation of the two substances by chromatography.

5) Synthesis of the three selected compounds

(in Polish) T

(in Polish) T

(in Polish) T

(in Polish) T

(in Polish) Feeding methods

 informative lecture

 explanation or clarification.

Seeking methods:

 laboratory exercises, experimets

observation and measurement

Exposing methods: show

(in Polish) The grade of the lecture consist of evaluation of written examination (50%) evaluating the effects of training in the knowledge and the laboratory exercises with written reports, (25%), classes (problem solving exercises) (25%).

A prerequisite for the exam aproach is to obtain credit from the laboratory and classes.

Effects of training in the collaborative work will be evaluated during laboratory exercises.

(in Polish) Lecture:

1) Alkanes and cycloalkanes. Cracking processes. Radical substitution reactions, halogenation of C (sp3)-H.

2) Halogen derivatives of alkanes, the polarization of the CX bond. Grignard reagents, nucleophilic substitution, nucleophilic reagents and their reactivity. Basicity and nucleophilicity. Mechanisms of nucleofilic substitution SN1, SN2 and elimination reactions E1 and E2. Zaitsev rule.

3) Alkenes and cycloalkenes. Geometric isomerism. Halogenation - electrophilic addition reactions, addition of HX reagents, reactions with oxidizing agents, free-radical polymerization, catalytic hydrogenation of alkenes. The stereochemistry of electrophilic addition reaction. The regiochemistry of HX addition to unsymmetrically substituted alkenes.

4) Alkynes. Reactions with HX reagents; catalyzed addition of water. Acidity of terminal alkynes; reactions with Grignard reagents

5) Dienes - structure, types. Conjugated dienes - isomerism s-cis and s-trans. Mesomerism. Electrophilic reagent addition reactions to conjugated dienes. Diels-Alder reaction.

6) Aromatic compounds, the concept of aromaticity, Hückel rule, resonance energy. reactivity of aromatic compounds. Electrophilic substitution: halogenation, nitration, sulfonation, alkylation, arylation. The role of the Lewis acid in electrophilic substitution. Electrophilic substitution mechanism. Isomerism of disubstituted benzene derivatives.

7) Alcohols and phenols. Effect of functional group-OH on the physico-chemical properties of alcohols, hydrogen bonding. Elimination and substitution reactions in a series of alcohols. The reactivity of the-OH: acidity, esterification, oxidation of alcohols. Polyhydroxy compounds. Acidity of phenols.

8)Ethers and epoxides. Thiols and sulfides. Synthesis, structure and reactivity.

9) Aliphatic and aromatic amines. Structure and bonding in amines. Basicity of amines - the impact of structure on the basicity of amines. Acylation of amines. Quaternary ammonium salts. The synthesis and reactions of arene diazonium salts. Azo dyes.

10) Aldehydes and ketones. The structure of the carbonyl group. Redox reactions. Nucleophilic addition of nucleophiles using nitrogen, oxygen, and carbon. The concept CH acidity, keto-enol tautomerism. Aldol-type condensations.

11) Aliphatic and aromatic carboxylic acids. The structure of a carboxyl group, a hydrogen bond in the carboxylic acids. Substituents effect on acidity, influence of inductive and mesomeric effect. The reactivity of the carboxyl group, esterification reaction, hydrolysis of esters.

12) Carboxylic acid derivatives and nucleophilic acyl substitution reactions. Chemistry of: acid halides, acid anhydrides, esters, amides, nitriles

Seminar / Class:

The aim of the seminar is to discuss the basic concepts presented during the lecture. Problem solving-classes teach how to apply the organic chemistry knowledge to solve the problems.

Laboratory:

1) Selection of a solvent for crystallization, crystallization of the substance, identification of substance using the melting point.

2) Distillation of the unknown substance and its identification using the boiling point and refractive index, separation of substances by the fractional distillation.

3) Separation of two substances by extraction.

4) The separation of the two substances by chromatography.

5) Synthesis of the three selected compounds

(in Polish) T

(in Polish) Feeding methods

 informative lecture

 explanation or clarification.

Seeking methods:

 laboratory exercises, experimets

observation and measurement

Exposing methods: show

(in Polish) The grade of the lecture consist of evaluation of written examination (50%) evaluating the effects of training in the knowledge and the laboratory exercises with written reports, (25%), classes (problem solving exercises) (25%).

A prerequisite for the exam aproach is to obtain credit from the laboratory and classes.

Effects of training in the collaborative work will be evaluated during laboratory exercises.

(in Polish) Lecture:

1) Alkanes and cycloalkanes. Cracking processes. Radical substitution reactions, halogenation of C (sp3)-H.

2) Halogen derivatives of alkanes, the polarization of the CX bond. Grignard reagents, nucleophilic substitution, nucleophilic reagents and their reactivity. Basicity and nucleophilicity. Mechanisms of nucleofilic substitution SN1, SN2 and elimination reactions E1 and E2. Zaitsev rule.

3) Alkenes and cycloalkenes. Geometric isomerism. Halogenation - electrophilic addition reactions, addition of HX reagents, reactions with oxidizing agents, free-radical polymerization, catalytic hydrogenation of alkenes. The stereochemistry of electrophilic addition reaction. The regiochemistry of HX addition to unsymmetrically substituted alkenes.

4) Alkynes. Reactions with HX reagents; catalyzed addition of water. Acidity of terminal alkynes; reactions with Grignard reagents

5) Dienes - structure, types. Conjugated dienes - isomerism s-cis and s-trans. Mesomerism. Electrophilic reagent addition reactions to conjugated dienes. Diels-Alder reaction.

6) Aromatic compounds, the concept of aromaticity, Hückel rule, resonance energy. reactivity of aromatic compounds. Electrophilic substitution: halogenation, nitration, sulfonation, alkylation, arylation. The role of the Lewis acid in electrophilic substitution. Electrophilic substitution mechanism. Isomerism of disubstituted benzene derivatives.

7) Alcohols and phenols. Effect of functional group-OH on the physico-chemical properties of alcohols, hydrogen bonding. Elimination and substitution reactions in a series of alcohols. The reactivity of the-OH: acidity, esterification, oxidation of alcohols. Polyhydroxy compounds. Acidity of phenols.

8)Ethers and epoxides. Thiols and sulfides. Synthesis, structure and reactivity.

9) Aliphatic and aromatic amines. Structure and bonding in amines. Basicity of amines - the impact of structure on the basicity of amines. Acylation of amines. Quaternary ammonium salts. The synthesis and reactions of arene diazonium salts. Azo dyes.

10) Aldehydes and ketones. The structure of the carbonyl group. Redox reactions. Nucleophilic addition of nucleophiles using nitrogen, oxygen, and carbon. The concept CH acidity, keto-enol tautomerism. Aldol-type condensations.

11) Aliphatic and aromatic carboxylic acids. The structure of a carboxyl group, a hydrogen bond in the carboxylic acids. Substituents effect on acidity, influence of inductive and mesomeric effect. The reactivity of the carboxyl group, esterification reaction, hydrolysis of esters.

12) Carboxylic acid derivatives and nucleophilic acyl substitution reactions. Chemistry of: acid halides, acid anhydrides, esters, amides, nitriles

Seminar / Class:

The aim of the seminar is to discuss the basic concepts presented during the lecture. Problem solving-classes teach how to apply the organic chemistry knowledge to solve the problems.

Laboratory:

1) Selection of a solvent for crystallization, crystallization of the substance, identification of substance using the melting point.

2) Distillation of the unknown substance and its identification using the boiling point and refractive index, separation of substances by the fractional distillation.

3) Separation of two substances by extraction.

4) The separation of the two substances by chromatography.

5) Synthesis of the three selected compounds